The structure-property relationship of oxovanadium(IV) complexes in the wall framework of PMOs and their catalytic applications

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• 作者：Shijian Zhou^a ; ^b ; Bangbang Wang^a ; Shuying Gao^a ; Yun Ding^a ; Yan Kong^a ; ^{kongy36@njtech.edu.cn}
• 关键词：Oxovanadium(IV) complexes ; Framework ; Periodically meosporous organosilicas (PMOs) ; Styrene oxidation
• 刊名：Applied Surface Science
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：397
• 期：Complete
• 页码：183-191
• 全文大小：1911 K
• 卷排序：397

文摘

The oxovanadium complexes were directly incorporated into the wall framework of PMOs instead of the pore channels by one-step synthesis process, partly avoiding the destruction of the mesoporous channels. The vanadium species in the framework of PMOs are highly stable as pseudotetrahedral monovanadate. These as-prepared V-PMO catalysts display high catalytic activity and stability in the styrene oxidation reaction.