Experimental and theoretical studies on the thermal decomposition of 1,1,2,2,3,3,4-heptafluorocyclopentane
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- 作者：Xiaomeng Zhoua ; zhouxm@nankai.edu.cn" class="auth_mail ; Dayong Lua ; Mingyong Chaob ; Weiwang Chena
- 关键词：1 ; 1 ; 2 ; 2 ; 3 ; 3 ; 4-Heptafluorocyclopentane ; Halon replacement ; Activation energy ; Pyrolysis ; Kinetics
- 刊名：Journal of Fluorine Chemistry
- 出版年：August 2014
- 年：2014
- 卷：164
- 期：Complete
- 页码：70-77
- 全文大小：2051 K
文摘
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Pyrolysis characteristics of F7A were studied under various temperatures.
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The lowest dissociation energy of F7A is proposed.
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Theoretical results calculated by Gaussian 03 agree well with experimental results.
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Thermal decomposition products and dissociation pathways of F7A were discussed.