Borohydride electrooxidation over Pt/C, AuPt/C and Au/C catalysts: Partial reaction pathways and mixed potential formation
详细信息 查看全文
- 作者：Zenonas Jusys ; zenonas.jusys@uni-ulm.de" class="auth_mail" title="E-mail the corresponding author ; R. Jü ; rgen Behm
- 关键词：Borohydride oxidation ; Deuterium labeling ; Online mass spectrometry ; Pt-based catalysts ; Alkaline solution ; Mixed potential
- 刊名：Electrochemistry Communications
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：60
- 期：Complete
- 页码：9-12
- 全文大小：541 K
文摘
- •
Borodeuteride oxidation over Pt/C, AuPt/C, and Au/C catalysts combined with online mass spectrometry
- •
Potential-induced reaction selectivity change from complete to incomplete on Pt-based catalysts
- •
Deuterium formation prevails on oxide covered catalysts
- •
Overpotential for borodeuteride oxidation and water reduction on Au/C catalyst
- •
Mixed potential formation and hydrogen evolution from water on Pt-based catalysts but not on Au/C catalyst