Synthesis, structures and catalytic activity of p-tolylimido rhenium(V) complexes incorporating quinoline-derived ligands

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• 作者：I. Gryca^a ; B. Machura^a ; ^{basia@ich.us.edu.pl} ; Lidia S. Shul&rsquo ; pina^b ; Georgiy B. Shul&rsquo ; pin^c ; ^d ; ^{Shulpin@chph.ras.ru}
• 关键词：Rhenium imido complexes ; X-ray structure ; DFT calculations ; Alcohols ; tert-Butyl hydroperoxide ; Oxidation
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：683-695
• 全文大小：2510 K
• 卷排序：455

文摘

New rhenium(V) complexes have been prepared. Structures have been studied by X-ray and DFT methods. Some complexes exhibited moderate activity in regioselective oxidation of hydrocarbons.