MLCT interaction in [Rh(II)2(CO3)4]4 −( x L)
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- 作者：Arnd Vogler
- 关键词：Photochemistry ; Rhodium(II) ; Carbonate ; Photoreduction of CO2 ; MLCT excitation
- 刊名：Inorganic Chemistry Communications
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：62
- 期：Complete
- 页码：5-7
- 全文大小：314 K
文摘
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[Rh(II)2(CO3)4]xLn− with L = H2O, N-methylpyrazinium+, N-methyl-4,4´-bipy+ have been studied.
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These complexes are characterized by MLCT interactions.
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With L = H2O a photolysis takes place.
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While Rh(II) is photoxidized, carbonate is photoreduced to CO.