Synthesis of a bimetallic P-N bridged rhodium (I)-ruthenium (II) complex: Application in the hydroformylation reaction
详细信息 查看全文
- 作者：Ksenia Kartashovaa ; b ; Sonia Mallet-Ladeiraa ; b ; M. Rosa Axeta ; b ; 1 ; rosa.axet@lcc-toulouse.fr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Bimetallic complex ; Hydroformylation ; Rhodium ; Ruthenium
- 刊名：Journal of Organometallic Chemistry
- 出版年：2015
- 出版时间：15 December 2015
- 年：2015
- 卷：799-800
- 期：Complete
- 页码：226-231
- 全文大小：653 K
文摘
- •
Synthesis of a novel cationic Rh–Ru complex displaying a Rh–Ru bond of 2.901(1) Ǻ.
- •
Application of the Ru–Rh complex as catalyst in the hydroformylation of 1-octene.
- •
Comparison with the respective mononuclear Ru and Rh complexes.
- •
NMR study of the rhodium–ruthenium complex under syngas pressure.
- •
Fragmentation of the bimetallic complex occurs under hydroformylation conditions.