Relative configuration of luminaolide

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• 作者：Norihito Maru ; Toshiyasu Inuzuka ; Keita Yamamoto ; Makoto Kitamura ; Peter J. Schupp ; Kaoru Yamada ; Daisuke Uemura
• 关键词：Luminaolide ; Coral larvae ; Enhancer ; Stereochemistry ; JBCA method
• 刊名：Tetrahedron Letters
• 出版年：2013
• 出版时间：14 August, 2013
• 年：2013
• 卷：54
• 期：33
• 页码：4385-4387
• 全文大小：758 K

文摘

The coral metamorphosis-enhancing compound luminaolide was isolated from the crustose coralline algae (CCA) Hydrolithon reinboldii, and was shown to 34-membered macrodiolide skeleton. The relative configuration of luminaolide was established based on ¹H-¹H coupling constants, steric information from ROESY and a J-based configuration analysis using long-range ¹H-¹³C coupling constants.