CTAB aggregation in aqueous solutions of ammonium based ionic liquids; conductimetric studies

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• 作者：Ali Modaressi ; Hocine Sifaoui ; Beata Grzesiak ; Rol ; Solim ; o ; Urszula Domanska ; Marek Rogalski
• 关键词：Ionic liquids ; Micelles ; Surfactants ; Critical micelle concentration ; Electrical conductivity
• 刊名：Colloids and Surfaces A: Physicochemical and Engineering Aspects
• 出版年：2007
• 出版时间：15 March 2007
• 年：2007
• 卷：296
• 期：1-3
• 页码：104-108
• 全文大小：410 K

文摘

The electrical conductivity/concentration data of aqueous solutions of n-hexadecyl-trimethylammonium bromide (CTAB), an cationic surfactant, with two ammonium based ionic liquids propyl-(2-hydroxyethyl)-dimethyl-ammonium bromide, (C3Br), butyl-(2-hydroxyethyl)-dimethyl-ammonium bromide, (C4Br) of high melting points (>373 K) were determined in the temperature range 298.15–328.15 K. These data were used to determining the critical micelle concentration (CMC) in function of concentration and temperature. The two ionic liquids and the surfactant have the same anion and the ammonium based cation. The influence of ionic liquids on the micellisation process of the CTAB is discussed.