Synthesis and characterization of heterobimetallic complexes with pyridyl selenolato ligands. Crystal structure of [{Pt(C₅H₄N)(SeC₅H₄N)(dppp)}ZnCl₂]

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• 作者：Rohit Singh Chauhan^a ; ^{rohit.chuhan@somaiya.edu} ; Neelam Shivran^b ; Alexandra M.Z. Slawin^c ; ^{amzs@st-andrews.ac.uk} ; J. Derek Woollins^c
• 关键词：Platinum ; Selenolate ; NMR ; X-ray ; Phosphines
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：830
• 期：Complete
• 页码：181-187
• 全文大小：679 K
• 卷排序：830

文摘

Reactions of [Pt(SeC5H4N)2(dppm)] with d10 metal system resulted [PtX2(dppm)]. Reactions of [Pt(SeC5H4N)2(dppp)] with d10 metal system yielded an additive product. Interaction between Pt-d10depends on the size of metal.