Highly efficient Ru/carbon catalysts prepared by pyrolysis of supported Ru complex towards the hydrogen production from ammonia borane
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- 作者：Miriam Navlani-Garcí ; aa ; Kohsuke Moria ; b ; c ; mori@mat.eng.osaka-u.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Ai Nozakia ; Yasutaka Kuwaharaa ; b ; Hiromi Yamashitaa ; b ; yamashita@mat.eng.osaka-u.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrogen production ; Ammonia borane ; Ru nanoparticles ; Metal complex ; Nanoparticle size
- 刊名：Applied Catalysis A: General
- 出版年：2016
- 出版时间：25 October 2016
- 年：2016
- 卷：527
- 期：Complete
- 页码：45-52
- 全文大小：1885 K
文摘
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Highly efficient Ru/carbon catalysts for the hydrogen production from ammonia borane were synthesized.
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Metal complex decomposition temperature plays a pivotal role in determining the catalysts features.
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A very high TOF number of 670 mol H2/mol metal min was achieved with the best performing catalyst.