Alumina sol-gel film is prepared on NdFeB magnets by electro-deposition and hydrothermal methods. The alumina sol (AS) film improves the corrosion resistance and thermal stability of NdFeB. The kinetics features of alumina sol particles under electric field are investigated. The phase transition from alumina particle to boehmite layers on AS film are studied. The AS film is useful for the preparation of no magnetic loss protection film on NdFeB magnets.