Synthesis and ionic transport mechanisms of α-LiAlO2
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Pure phase α-LiAlO2 is synthesized.

Room-temperature ionic conductivity of the α-LiAlO2 sample is as low as 10− 21 S·cm− 1.

Defect formation and migration energy of α-LiAlO2 with bias voltage are calculated.

Bias voltage can enhance conductivity of α-LiAlO2.

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