Effects of the substitution of P2O5 with B2O3 on the structure, iron valence, thermal and crystallization behavior of lithium-iron-phosphate glasses
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- 作者：Shiquan Liu ; liusq_ujn@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; mse_liusq@ujn.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Ruijuan Yang ; Yinghui Wang
- 关键词：Lithium-iron-phosphate glass ; Structure ; Iron state ; Crystallization ; LiFe(II)PO4
- 刊名：Journal of Non-Crystalline Solids
- 出版年：2016
- 出版时间：1 December 2016
- 年：2016
- 卷：453
- 期：Complete
- 页码：158-163
- 全文大小：971 K
文摘
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The substitution of P2O5 with B2O3 in lithium-iron-phosphate glass.
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The formation of a second phase with lower transition and crystallization temperatures.
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The fraction of Fe(II) increases with the addition of B2O3.
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The crystallization of LiFe(II)PO4 and Li3Fe2(PO4)3 phases.