The volume change ratio of PMMA at 12 MPa has the most significant increment, instead of that at 20 MPa.
Tg of PMMA decreased from 380.5 to 311.4 K withCO2 pressure 0.1–12 MPa, and increased from 311.4 to 323.1 K with 12–22 MPa.
When CO2 pressure is beyond 12 MPa, hydrostatic pressure has a more significant effect on swelling ratio than swelling.
The g" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0896844615302151&_mathId=si1.gif&_user=111111111&_pii=S0896844615302151&_rdoc=1&_issn=08968446&md5=43049a56100f51066de64d2608745823" title="Click to view the MathML source">Tsat−pCO2 curve has similar change with the g" data-mathURL="/science?_ob=MathURL&_method=retrieve&_eid=1-s2.0-S0896844615302151&_mathId=si2.gif&_user=111111111&_pii=S0896844615302151&_rdoc=1&_issn=08968446&md5=2751382d08fe9d5c7ff335264c66ecbe" title="Click to view the MathML source">Tg−pCO2 curve.