Extending the range of stabilised, primary and secondary phosphanes containing ferrocenyl or ruthenocenyl groups
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- 作者：Toshie Asamizua ; William Hendersona ; w.henderson@waikato.ac.nz" class="auth_mail ; Brian K. Nicholsona ; Evamarie Hey-Hawkinsb
- 关键词：Primary phosphanes ; Secondary phosphanes ; Ferrocene compounds ; Ruthenocene compounds ; Crystal structure
- 刊名：Inorganica Chimica Acta
- 出版年：1 April, 2014
- 年：2014
- 卷：414
- 期：Complete
- 页码：181-190
- 全文大小：677 K
文摘
Alkylation reactions of FcCH2P(CH2OH)2 [Fc = (畏5-C5H5)Fe(畏5-C5H4)] with MeI or p-BrCH2C6H4NO2, or of CyP(CH2OH)2 with [FcCH2NMe3+]I鈭?/sup> gave hydroxymethylphosphanes FcCH2PR(CH2OH) (R = Me, Cy or p-O2NCH2C6H4) which were converted to the new secondary phosphanes FcCH2PHR on treatment with Na2S2O5. A series of longer-chain ferrocenylalkyl primary phosphanes Fc(CH2)nPH2 was also prepared by reactions of the bromoalkylferrocenes Fc(CH2)nBr (n = 4, 6 or 11) with P(CH2OH)3 to give intermediate hydroxymethylphosphanes Fc(CH2)nP(CH2OH)2, followed by reaction with Na2S2O5. Fc(CH2)6PH2 was converted into its crystalline BH3 adduct, which was structurally characterised. The synthesis of the new ruthenocene (Rc)-derived primary phosphane RcCH2PH2, the first example of a ruthenocene-derived primary phosphane, is also reported.