Chemostratigraphic and U-Pb geochronologic constraints on carbon cycling across the Silurian-Devonian boundary
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文摘

We document a global +5% δ13C excursion in the Silurian–Devonian Helderberg Group.

We develop U–Pb ages on 6 Helderberg ashes via CA-ID-TIMS on volcanic zircon.

U–Pb ages include dates on the stratigraphically lowest Devonian ashes yet developed.

We estimate the Silurian–Devonian boundary age to be 421.3±1.2 Ma.

A steady-state model explains the excursion if [DIC] was less than 2× modern levels.

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