Electro-catalytic conversion of ethanol in solid electrolyte cells for distributed hydrogen generation
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- 作者：HyungKuk Jua ; Sarbjit Giddeya ; Sukhvinder P.S. Badwala ; Sukhvinder.Badwal@csiro.au" class="auth_mail" title="E-mail the corresponding author ; Roger J. Mulderb
- 关键词：Electrocatalyst ; PEM Electrolysis ; Bioethanol reforming ; Ethanol oxidation mechanism ; Catalytic fuel processing
- 刊名：Electrochimica Acta
- 出版年：2016
- 出版时间：10 September 2016
- 年：2016
- 卷：212
- 期：Complete
- 页码：744-757
- 全文大小：3043 K
文摘
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Ethanol assisted water electrolysis reduces electric energy input by more than 50%.
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Partial oxidation of ethanol leads to formation of undesired chemicals.
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Degradation occurs due to formation of by-products and poisoning of catalyst.
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Better catalyst has the potential to increase ethanol to H2 conversion efficiency.
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A plausible ethanol electro-oxidation mechanism has been proposed