Studies on intramolecular electron transfer reaction in donor-spacer-acceptor systems in room-temperature ionic liquids
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- 作者：Prabhat Kumar Sahu ; Sudhir Kumar Das ; Moloy Sarkar ; msarkar@niser.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Photoinduced electron transfer ; Room-temperature ionic liquids ; Time-resolved fluorescence measurements ; Solvation dynamics
- 刊名：Journal of Molecular Liquids
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：214
- 期：Complete
- 页码：24-31
- 全文大小：1008 K
文摘
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Intramolecular PET studies in two flexible DSA systems have been examined in RTILs.
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PET rates are found to be hindered in the RTILs compared to that in acetonitrile.
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The kinship between rate of solvation and the rate of electron transfer in RTILs is demonstrated.