Ferromagnetic mixed tribridged dinuclear copper(II) complex [Cu2(OAc)2(OH)(dpa)2]PF6 · H2O (dpa = 2,2′-dipyridyla
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- 作者：Habibar Chowdhury ; Sk Hafijur Rahaman ; Rajarshi Ghosh ; Sajal K. Sarkar ; Montse Corbella ; Barindra K. Ghosh
- 关键词：Dinuclear copper(II) ; 2 ; 2′ ; -Dipyridylamine ; Superstructure ; Ferromagnetism ; Luminescence
- 刊名：Inorganic Chemistry Communications
- 出版年：2006
- 出版时间：December 2006
- 年：2006
- 卷：9
- 期：12
- 页码：1276-1280
- 全文大小：568 K
文摘
A new dinuclear complex [Cu2(OAc)2(OH)(dpa)2] PF6 · H2O (1) is prepared and structurally and magneto-structurally characterized. The monocationic core contains one acetate in familiar bidentate η1:η1:μ2-bridge and another in the rare monoatomic bridge along with one hydroxo intermediary. 1 packs through N–H…O and O–H…O hydrogen bonds and π…π interaction resulting a 3D supramolecular continuum and displays high-energy intraligand 1(π − π*) fluorescence and intraligand 3(π − π*) phosphorescence in glassy solution.