A convenient and practical method for the selective preparation of deuterofluorocarbons
详细信息 查看全文
- 作者：David P. Richardson
- 关键词：Deuteration ; Perfluoroalkanes ; Deuteroperfluroroalkanes ; Iodoperfluoroalkanes ; Zinc ; Zinc chloride ; 19F NMR spectroscopy
- 刊名：Journal of Fluorine Chemistry
- 出版年：2015
- 出版时间：December 2015
- 年：2015
- 卷：180
- 期：Complete
- 页码：208-215
- 全文大小：527 K
文摘
- •
- <p id="par0005">Reaction conditions for mild iodine/deuterium exchange in perfluoroalkanes were developed.p>
- •
- <p id="par0010">Linear 1-deuterononafluorobutane, 1-deuteroundecafluoropentane and 1-deuterotridecafluorohexane were synthesized.p>
- •
- <p id="par0015">Reaction required only zinc metal and D2O at 170 °C in a sealed tube.p>
- •
- <p id="par0020">The non-perfluorinated target 6-deutero-1,1,1,2,2,3,3,4,4-nonafluorohexane could be synthesized with this method.p>