Thermodynamic description of the solvophobic effect in ionic liquids
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- 作者：I.A. Sedov ; igor_sedov@inbox.ru" class="auth_mail" title="E-mail the corresponding author ; B.N. Solomonov
- 关键词：Solvophobic effect ; Ionic liquids ; Enthalpy of solvation ; Gibbs free energy of solvation
- 刊名：Fluid Phase Equilibria
- 出版年：2016
- 出版时间：15 October 2016
- 年：2016
- 卷：425
- 期：Complete
- 页码：9-14
- 全文大小：781 K
文摘
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We analyzed literature data on the thermodynamic functions of solvation of various species in ILs.
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Gibbs free energy vs enthalpy of solvation plots indicate strong solvophobic effects in aprotic Ils
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Strength of the solvophobic effects in ILs correlates with the concentration of ions.