Standard molar Gibbs free energy and enthalpy of solvation of low polar solutes in formamide derivatives at 298 K
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- 作者：I.A. Sedov ; igor_sedov@inbox.ru" class="auth_mail" title="E-mail the corresponding author ; T.I. Magsumov ; M.A. Stolov ; B.N. Solomonov
- 关键词：Solution calorimetry ; Solvation ; Standard enthalpy ; Standard Gibbs free energy ; Binary solvents ; Solvophobic effect
- 刊名：Thermochimica Acta
- 出版年：2016
- 出版时间：10 January 2016
- 年：2016
- 卷：623
- 期：Complete
- 页码：9-14
- 全文大小：568 K
文摘
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Standard molar enthalpies of solution of low polar solutes in NMF were measured.
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Limiting activity coefficients in NMF were measured.
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The solvophobic effects are present but weaker in NMF than in formamide.
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We can tune the solvophobic effects by mixing NMF or formamide with other solvents.