Metallacumulenes: from vinylidenes to metal polycarbides

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• 作者：Selegue ; John P.
• 关键词：Metallacumulenes ; Vinylidenes ; Metal polycarbides ; Allenylidenes ; Metal carbides
• 刊名：Coordination Chemistry Reviews
• 出版年：2004
• 出版时间：August, 2004
• 年：2004
• 卷：248
• 期：15-16
• 页码：1543-1563
• 全文大小：551 K

文摘

Metallacumulenes and carbide complexes exhibit diverse structures and modes of reactivity. This review presents an overview of work in the author's research group on vinylidene complexes of group 6 and 8 metals, allenylidene and butatrienylidene complexes of group 8 metals, and metal carbide, bicarbide and tricarbide complexes of group 6, 7 and 8 metals.