A re-investigation of the reaction of [RuCl2(CO)3]2 with C5H5(Me3Si) X-ray structure determination of [Ru(CO)3(η-C
详细信息 查看全文
- 作者：Griffith ; Christopher S. ; Koutsantonis ; George A. ; Raston ; Colin L. ; Selegue ; John P. ; Skelton ; Brian W. ; et. al.
- 关键词：Ruthenium anion ; Carbonyl ; Silicon ; Cyclopentadienyl ; Starting material ; Superlattice symmetry ; Ruthenium cation
- 刊名：Journal of Organometallic Chemistry
- 出版年：1996
- 出版时间：July 12, 1996
- 年：1996
- 卷：518
- 期：1-2
- 页码：197-202
- 全文大小：339 K
文摘
The reaction of [RuCl2(CO)3]2 with C5H5(SiMe3) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)3(η-C5H5)][fac-RuCl3(CO)3], 1, and [RuCl(CO)2(η-C5H5)], 2, in 68 % and 12 % yield respectively. The reaction of CO with commercially available hydrated OsCl3 gives [OsCl2(CO)3]2 in 44 % yield. The crystal structure of [Ru(CO)3(η-C5H5)][fac-RuCl3(CO)3] is reported; superlattice symmetry is observed.