Li2O–PbO–B2O3–P2O5: MnO glasses were developed by melt quenching method.
Spectroscopic and dielectric properties of MnO doped glasses were investigated.
EPR spectra confirmed the existence of Mn2+ and Mn3+ ions in the glass matrix.
Glass mixed with 3 mol% of MnO exhibited the highest conductivity.
The semiconducting nature of the glasses rises gradually with the hike in MnO.