Gas-phase study of metal complexes with redox-active ligands
详细信息 查看全文
- 作者：Ghazaleh Yassaghi ; Lucie Ja&scaron ; í ; ková ; Jana Roithová ; ; roithova@natur.cuni.cz" class="auth_mail" title="E-mail the corresponding author
- 关键词：Copper ; Density functional theory calculations ; Infrared spectra ; Mass spectrometry ; Phenols ; Quinones ; Redox-active ligands ; Semiquinones
- 刊名：International Journal of Mass Spectrometry
- 出版年：2016
- 出版时间：20 August 2016
- 年：2016
- 卷：407
- 期：Complete
- 页码：92-100
- 全文大小：2590 K
文摘
- •
Redox-active metal complexes were studied by IRMPD spectroscopy, DFT calculations, and mass spectrometry.
- •
C
O stretching mode is a clear spectral marker of redox activity in phenanthraquinone complexes.- •
Oxidation of maltol by copper(II) in their complex was studied by collision induced dissociation experiments.