Synthesis and X-ray crystallographic characterization of [In(tsalen)(OAc)] (tsalen = N,N′-ethylenebis(thiosalicylideneimine))

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• 作者：Michael T. Sullivan ; Nilmini K. Senaratne ; David M. Eichhorn ; ^{david.eichhorn@wichita.edu" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Indium complex ; Thiolate ligand ; Imine ligand ; Crystal structure ; Acetate ligand
• 刊名：Polyhedron
• 出版年：2016
• 出版时间：16 August 2016
• 年：2016
• 卷：114
• 期：Complete
• 页码：152-155
• 全文大小：797 K

文摘

The first synthesis and crystallographic characterization of a main-group metal complex of the N₂S₂ ligand N,N′-ethylenebis(thiosalicylideneimine) (tsalen) is reported, with the isolation and characterization of the indium(III) compound [In(tsalen)(OAc)]. This compound has been crystallographically characterized and is shown to have a distorted trigonal bipyramidal geometry with a ligand that is unusually distorted from planarity. A byproduct of the synthesis, [In(en)₂(OAc)₂](OAc), has also been isolated and characterized.