Bottom-up construction of highly photoactive dye-sensitized titania using Ru(II) and Ir(III) complexes as building blocks
详细信息 查看全文
- 作者：Marisa Rico-Santacruza ; Á ; ngel E. Sepú ; lvedab ; Cintia Ezquerrob ; Elena Serranoa ; Elena Lalindeb ; Jesú ; s R. Berenguerb ; jesus.berenguer@unirioja.es" class="auth_mail" title="E-mail the corresponding author ; Javier Garcí ; a-Martí ; neza ; j.garcia@ua.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Dye-sensitization ; Hybrid metal complex-titania ; Band-gap reduction ; Visible light activity ; Coordination chromophore
- 刊名：Applied Catalysis B: Environmental
- 出版年：2017
- 出版时间：January 2017
- 年：2017
- 卷：200
- 期：Complete
- 页码：93-105
- 全文大小：4009 K
文摘
- •
A new strategy for building dye-sensitized mesoporous titanias with anatase structure from the bottom-up.
- •
One-pot co-condensation of TBOT with different functionalized coordination dyes.
- •
In-situ incorporation of the chromophores while crystallizing the semiconductor matrix.
- •
Photoactivity enhancenment under UV and visible irradiation.
- •
Exceptional stability against both photodegradation and leaching.