Template-free coordination-driven self-assembly of discrete hexanuclear prismatic cages employing half-sandwich octahedral RuII2 acceptors and triimidazole donors
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- 作者：Aderonke Ajibola Adeyemo ; Sankarasekaran Shanmugaraju ; Dipak Samanta ; Partha Sarathi Mukherjee ; psm@ipc.iisc.ernet.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Self-assembly ; p-Cymene ruthenium(II) ; Triimidazole donors ; Supramolecular chemistry ; Cages
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：30 January 2016
- 年：2016
- 卷：440
- 期：Complete
- 页码：62-68
- 全文大小：2132 K
文摘
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Four hexanuclear trigonal prismatic cages have been synthesized.
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The cages have been characterised by IR spectroscopy, NMR, ESI-MS and geometry optimization.
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The self-selection of single (C3-symmetric) conformational isomeric cages as the only product is an interesting observation.