Gold-catalyzed selectivity-switchable oxidation of benzyl alcohol in the presence of molecular oxygen
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- 作者：Jinyan Sun ; Xinli Tong ; tongxinli@tju.edu.cn" class="auth_mail" title="E-mail the corresponding author ; Zonghui Liu ; Shengyun Liao 18202587221@163.com" class="auth_mail" title="E-mail the corresponding author ; Xuli Zhuang ; Song Xue
- 关键词：Selectivity-switchable ; Oxidation ; Benzyl alcohol ; Graphene ; Molecular oxygen
- 刊名：Catalysis Communications
- 出版年：2016
- 出版时间：5 October 2016
- 年：2016
- 卷：85
- 期：Complete
- 页码：70-74
- 全文大小：373 K
文摘
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A product selectivity-switchable oxidation of benzyl alcohol has been developed.
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96.2% conversion and 99.9% selectivity of methyl benzoate is obtained in methanol.
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89.1% conversion and 87.5% selectivity of benzaldehyde is attained in n-butanol.
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A possible reaction mechanism for the oxidation of benzyl alcohol is proposed.