Discharge/charge reaction mechanism of a pyrite-type FeS₂ cathode for sodium secondary batteries

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• 作者：Ayuko Kitajou ; Junpei Yamaguchi ; Satoshi Hara ; Shigeto Okada
• 关键词：FeS2 ; Pyrite ; Conversion reaction ; Na-ion battery ; XANES
• 刊名：Journal of Power Sources
• 出版年：1 February, 2014
• 年：2014
• 卷：247
• 期：Complete
• 页码：391-395
• 全文大小：1191 K

文摘

The structure changes of iron disulfide (FeS₂) during discharge/charge process were investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and synchrotron-based X-ray adsorption near the edge structure (XANES). Although the cyclability of the FeS₂/Na battery is poor, FeS₂/Na battery has a large first discharge capacity of 758聽mA聽h聽g^鈭?. It corresponds to 85% of the theoretical capacity based on the 4.0 Na reaction per FeS₂ (893聽mA聽h聽g^鈭?). According to the Fe K-edge XANES spectra of discharged FeS₂ pellets, there were no clear traces of iron valence change. However, the clear S K-edge jump shifted to lower energy with increasing Na content in FeS₂. This is because the binding energy of S 1s electrons decrease as the oxidation number of S decreases, suggesting that the charge neutrality of the cathode after 2.0 Na discharge is kept by an S valence change from (S-S)^{2鈭?/sup> to S2鈭?/sup>. Moreover, Na₂S diffraction peaks were detected at the 3.0 Na discharged state as a trace of Na conversion reaction in the FeS₂ cathode.}