Synthesis, crystal structure and properties of a Zn(II) complex with a new N,N,O-tridentate chelate ligand

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• 作者：Shanji Li ; Jiang Lu ; Hui Liang ; Shiliang Han ; Xiang Zhou
• 关键词：Zinc complex ; Benzimidazole ; 8-Hydroxyquinadine ; Molecular structure ; Properties
• 刊名：Inorganic Chemistry Communications
• 出版年：2008
• 出版时间：June 2008
• 年：2008
• 卷：11
• 期：6
• 页码：662-664
• 全文大小：246 K

文摘

A new N,N,O-tridentate chelate ligand, namely 2-(benzimidazol-2-yl)-8-octyloxyquinoline, has been synthesized with 8-hydroxyquinadine and o-phenylenediamine as the starting materials. The obtained ligand reacts with diethylzinc to give a neutral Zn(II) complex. The molecular structure of the complex has been determined by X-ray crystallography. The preliminary investigations on the thermal, electrochemical and luminescent properties of the complex are presented.