A spherical molecular assembly formed by the interplay of hydrophobic and hydrogen bonding interactions. Formation of a hexameric ball
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- 作者：Kenta Goto ; Yuji Miyahara ; Teruo Shinmyozu
- 刊名：Tetrahedron Letters
- 出版年：2010
- 出版时间：3 February 2010
- 年：2010
- 卷：51
- 期：5
- 页码：832-835
- 全文大小：302 K
文摘
A six-membered ball-like supramolecular structure of 1c was obtained by the interplay of hydrophobic and hydrogen bonding interactions. Preferred H-bonding connectivity and the proximate side-chain groups in a hydrophobic core stabilized to form the ball structure as revealed by making a comparison with the linear tape structure in the crystal polymorph of 1c.