Three various double emulsions (O1/W/O2) made by the double emulsion stirring method.
Solvent – free PAN hollow microspheres made by the supercritical drying process.
The skin-core structure of Pre-oxidation microspheres is associated with pre-oxidation conditions.
Pre-oxidation microspheres’ have remarkable advantages of pressure-resistance comparing to the plastic ones.
Pre-oxidation PAN microspheres at 300 °C have best mechanical performance than the others.