文摘
Four oxacalix[4]arene derivatives, in which 1,3-dinitrobenzene units and 1,3-di-tert-butylbenzene units are incorporated in alternating order, were synthesized by aromatic nucleophilic substitution. The introduction of the tert-butyl groups increased the stability of the macrocycles against nucleophilic C–O bond cleavage. X-ray crystal structure analyses reveal that the oxacalixarenes adopt an unsymmetrical 1,3-alternate conformation. The bulky substituents did not disturb the conjugation between the bridging oxygen atoms and the dinitrobenzene rings.