Probing effective photocorrosion inhibition and highly improved photocatalytic hydrogen production on monodisperse PANI@CdS core-shell nanospheres
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- 作者：Chao Wanga ; Li Wanga ; b ; Jun Jina ; Jing Liua ; Yu Lia ; yu.li@whut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; manliyu2002@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Min Wua ; Lihua Chena ; Binjie Wangd ; Xiaoyu Yanga ; Bao-Lian Sua ; b ; c ; baoliansu@whut.edu.cn" class="auth_mail" title="E-mail the corresponding author ; bls26@cam.ac.uk" class="auth_mail" title="E-mail the corresponding author ; bao-lian.su@unamur.be" class="auth_mail" title="E-mail the corresponding author
- 关键词：PANI ; CdS ; Core-shell nanospheres ; Photocorrosion inhibition ; Photocatalytic hydrogen production
- 刊名：Applied Catalysis B: Environmental
- 出版年：2016
- 出版时间：5 July 2016
- 年：2016
- 卷：188
- 期：Complete
- 页码：351-359
- 全文大小：3240 K
文摘
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PANI@CdS core-shell nanospheres via a proton doped in-situ polymerization technique.
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PANI@CdS core-shell nanospheres demonstrate highly enhanced photocorrosion inhibition and photocatalytic hydrogen production.
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Cd bonds are newly formed between PANI shell and CdS core, leading to enhanced photocorrosion inhibition.
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The photogenerated holes migrate from VB of CdS to HOMO of PANI, leading to enhanced photocatalytic hydrogen production.