Calcium and aluminium-based fillers as flame-retardant additives in silicone matrices II. Analyses on composite residues from an industrial-based pyrolysis test

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• 作者：Siska Hamdani-Devarennes^a ; Audrey Pommier^a ; Claire Longuet^a ; Jos&#xe9 ; -Marie Lopez-Cuesta^a ; ^{jose-marie.lopez-cuesta@mines-ales.fr" rel="nofollow} ; Fran&#xe7 ; ois Ganachaud^b ; ^{francois.ganachaud@enscm.fr" rel="nofollow}
• 关键词：Silicone ; Fillers ; Calcium ; Aluminum ; Pyrolysis ; Residue
• 刊名：Polymer Degradation and Stability
• 出版年：2011
• 出版时间：September 2011
• 年：2011
• 卷：96
• 期：9
• 页码：1562-1572
• 全文大小：1861 K
• ISSN：S0141391011002011

文摘

The second part of this series, devoted to the study of model fire-resistant silicone composites filled with calcium or aluminium-based material which would meet cable industry specifications, focuses on residues obtained after extreme pyrolysis adapted from the NFC 32070 CR1 French standard. Several methods of analysis (among them ESEM, EDX, XRD, Hg pycnometer, and compression tests) have been carried out in order to investigate the microstructure, volume variation, and compression behaviour of silicone composite residues. Calcium-based fillers produced more cohesive residues than aluminium-based fillers. Indeed, the co-crystallisation taking place during pyrolysis, as shown in the first part of this series (Hamdani, S. et al., Polym Degrad Stab, 2010, 95, 1911–1919), produced a dense and strong residue. The strong internal porosity and absence of new crystal formation in residues of aluminium-based filled composites resulted in their low compressive resistance. In addition, water release during the degradation of the latter fillers, favoured residue expansion, high interior porosity and thus weak compression resistance.