NiFe-LDH/rGO catalyst was obtained via solvothermal and chemical reduction method.
OER and ORR activities of NiFe-LDH/rGO in alkaline media were firstly studied.
NiFe-LDH/rGO shows better OER activity with a lower onset overpotential of 240 mV.
NiFe-LDH/rGO gives a 0.796 V ORR onset potential mainly involving the 4e pathway.