Van-der-Waals based solvates of C60 with CBr2Cl2 and CBr2(CH3)2
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- 作者：Jin Yea ; Maria Barrioa ; René ; Cé ; olina ; b ; Navid Qureshic ; Ivo B. Rietveldd ; Josep Lluí ; s Tamarita ; josep.lluis.tamarit@upc.edu" class="auth_mail" title="E-mail the corresponding author
- 刊名：Chemical Physics
- 出版年：2016
- 出版时间：30 September 2016
- 年：2016
- 卷：477
- 期：Complete
- 页码：39-45
- 全文大小：5123 K
文摘
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Unstable in air cubic co-crystals of C60·12CCl2Br2 and C60·12CBr2(CH3)2 were grown in saturated solutions.
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Cubic co-crystals transform into the stable hexagonal co-crystals C60·2CCl2Br2 or C60·2CBr2(CH3)2.
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V/Z for cubic and hexagonal co-crystals depend exclusively on the vdW volumes of the constituents.