Synthesis, reactivity and crystal structures of various solvates of fac-tris(trimethylphosphine)trichloroiridium

详细信息    查看全文

• 作者：Joseph S. Merola ; ^{jmerola@vt.edu} ; Marion A. Franks ; Joy F. Frazier
• 关键词：Phosphine iridium complexes ; Iridium chloride complexes ; Iridium complex isomers ; Crystal packing forces ; Iridium phosphine chlorides
• 刊名：Polyhedron
• 出版年：2013
• 出版时间：30 April, 2013
• 年：2013
• 卷：54
• 期：Complete
• 页码：67-73
• 全文大小：1138 K

文摘

The synthesis of fac-tris(trimethylphosphine)iridiumtrichloride is reported and the crystal structure of five different solvates of this compound are analyzed. Compared with the idealized structure calculated with DFT methods, bond angles and distances differ considerably for all of the solvates examined. The utility of fac-tris(trimethylphosphine)iridiumtrichloride for the synthesis of organometallic compounds of iridium(III) is also demonstrated.