“Surfactant treatment” method to prepare GO in organic solvents is presented. DDAB was attached onto the GO sheets via ionic interactions by mild sonication. A PCE of 3.67% was obtained by doping 0.5 mg/mL GO:DDAB in P3HT:PC61BM. A PCE of 7.96% was obtained by doping GO:DDAB in PTB7:PC71BM. Surfactant-treated GO in organic solvent paves a way for high-efficiency OSC.