Chalcogenoacyl-bridged derivatives of the unsaturated carbyne complex [Mo₂(η⁵-C₅H₅)₂(μ-CPh)(μ-PCy₂)(CO)₂]

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• 作者：M. Á ; ngeles Alvarez ; M. Esther Garcí ; a ; Sonia Mené ; ndez ; Miguel A. Ruiz ; ^{mara@uniovi.es}
• 关键词：Molybdenum ; Metal&ndash ; metal interactions ; Phosphorus ligands ; Carbonyl complexes ; Chalcogenoacyl ligands ; Carbyne complexes
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 January 2017
• 年：2017
• 卷：828
• 期：Complete
• 页码：24-29
• 全文大小：722 K
• 卷排序：828

文摘

Elemental S and Se add easily to the title complex to build chalcogenoacyl ligands. Carbyne-chalcogen coupling yields μ-η2:η2-bound chalcogenoacyl ligands. 5-electron donor chalcogenoacyl ligands to saturate the title complex.