Nonheme iron complex-catalyzed efficient alcohol oxidation by t-BuOOH with N-hydroxyphthalimide (NHPI) as co-catalyst: Implication of high valent iron-oxo species
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- 作者：Jeong Mi Baea ; Myoung Mi Leea ; ohno801126@nate.com" class="auth_mail" title="E-mail the corresponding author ; Seul Ah Leea ; Sun Young Leea ; Kwon Hee Boka ; Jinheung Kimb ; Cheal Kima ; chealkim@seoultech.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Nonheme iron complexes ; Alcohol oxidation ; High-valent iron-oxo species ; tert-Butyl hydroperoxide ; Imidazole ; N-hydroxyphthalimide
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 September 2016
- 年：2016
- 卷：451
- 期：Complete
- 页码：8-15
- 全文大小：721 K
文摘
- •
Two iron catalysts displayed efficient catalysis in oxidation of various alcohols.
- •
Reactive oxidants are FeIV
O species, alkoxy radical (RO), and PINO.- •
Presence of imidazole increases formation of FeV
O intermediate.