Reduced graphene oxide (rGO) was decorated with metallic nanoparticles.
Ni/rGO, Ni/Pd/rGO and Ni/Ag/Pd/rGO hybrids were synthesized.
High hydrogen adsorption capability was observed at ambient environment.
Enhancement on H2 storage performance was attributed to the spillover mechanism.
Composition of the metallic NPs affects H2 adsorption/desorption reversibility.