Synthesis of N-aryl and N-heteroaryl hydroxylamines via partial reduction of nitroarenes with soluble nanoparticle catalysts

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• 作者：Jefferson H. Tyler ; S. Hadi Nazari ; Robert H. Patterson ; Venkatareddy Udumula ; Stacey J. Smith ; David J. Michaelis ; ^{dmichaelis@chem.byu.edu}
• 关键词：Hydroxylamine ; Nanoparticle ; Nitroarene ; Chemoselective ; Catalysis
• 刊名：Tetrahedron Letters
• 出版年：2017
• 出版时间：4 January 2017
• 年：2017
• 卷：58
• 期：1
• 页码：82-86
• 全文大小：1159 K
• 卷排序：58

文摘

Selective partial reduction of nitroarenes to hydroxylamines. High functional group tolerance for nitro reduction. Heteroaromatic hydroxylamines synthesized in high yield. Nanoparticle solubility impacts product selectivity.