Cu3(1,3,5-benzenetricarboxylate)2 metal-organic framework: A promising anode material for lithium-ion battery
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- 作者：Sandipan Maitia ; b ; Atin Pramanika ; b ; Unnikrishnan Manjua ; 1 ; Sourindra Mahantya ; b ; s_mahanty@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; mahanty@cgcri.res.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Metal organic framework (MOF) ; Cu-1 ; 3 ; 5-benzenetricarboxylate ; Lithium-ion battery
- 刊名：Microporous and Mesoporous Materials
- 出版年：2016
- 出版时间：15 May 2016
- 年：2016
- 卷：226
- 期：Complete
- 页码：353-359
- 全文大小：1780 K
文摘
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Solvothermal synthesis of mesoporous Cu3(1,3,5-benzenetricarboxylate)2 MOF.
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First report as lithium-ion battery anode material.
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A capacity of 740 mAhg−1, highest for MOF anodes, could be achieved with 70% retention after 50 cycles.
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Sustenance of MOF network upon cycling.
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A mechanism involving redox participation of the organic moiety is proposed.