Reaction of dichloromethane under non-oxidative conditions in a dielectric barrier discharge reactor and characterisation of the resultant polymer
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- 作者：Vaibhav Gaikwada ; 1 ; Eric Kennedya ; Eric.Kennedy@newcastle.edu.au" class="auth_mail" title="E-mail the corresponding author ; John Mackiea ; Clovia Holdsworthb ; Scott Molloya ; Sazal Kundua ; Michael Stockenhubera ; Bogdan Dlugogorskic
- 关键词：Dichloromethane ; Non-oxidative treatment ; Dielectric barrier discharge ; Polymer characterisation ; Quantum chemistry
- 刊名：Chemical Engineering Journal
- 出版年：2016
- 出版时间：15 April 2016
- 年：2016
- 卷：290
- 期：Complete
- 页码：499-506
- 全文大小：1023 K
文摘
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Non-oxidative treatment of DCM is explored using non-equilibrium plasma.
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The reaction mechanism relies on experimental data and quantum chemical analysis.
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Comprehensive mass balance for the reaction is provided.
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DCM is converted to an environmentally benign and potentially useful polymer.
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Characterisation of the polymer structure based on NMR analyses is presented.