Catalytic conversion of glycerol to polymers in the presence of ammonia
详细信息 查看全文
- 作者：Gizelle Sá ; ncheza ; Vaibhav Gaikwada ; Clovia Holdsworthb ; Bogdan Dlugogorskic ; Eric Kennedya ; Michael Stockenhubera ; michael.stockenhuber@newcastle.edu.au" class="auth_mail" title="E-mail the corresponding author
- 关键词：Polymers ; Glycerol conversion ; Ammonia ; Iron catalyst
- 刊名：Chemical Engineering Journal
- 出版年：2016
- 出版时间：1 May 2016
- 年：2016
- 卷：291
- 期：Complete
- 页码：279-286
- 全文大小：880 K
文摘
- •
First synthesis of polymers from glycerol and ammonia over an iron catalyst.
- •
Characterisation revealed unsaturated, amido and ester functionalities.
- •
Unsaturated, branched and cross-linked structures were present in the polymer.
- •
Oxidation of glycerol dehydration products is required for the polymerisation.