Self-assembly and morphology change of four organic-polyoxometalate hybrids with different solid structures from 2D lamellar to 3D hexagonal forms

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• 作者：Chunxia TAN ^{tancx@sina.com}
• 关键词：Organic-polyoxometalates ; Self-assembly ; Morphology ; Lamellar structure ; Hexagonal structure
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：1130
• 期：Complete
• 页码：276-283
• 全文大小：1743 K
• 卷排序：1130

文摘

Four hybrids containing europium and polymolybdate clusters were synthesized. Flower, deformed spherical and hexagonal self-assembly morphology of four hybrids were investigated by SEM and TEM. Relevance between self-assembly behaviors with different polyanions was explored. Solid accumulation from ordered 2D layered to 3D hexagon structure was explained.