Layered Li(Ni_0.5−xMn_0.5−xM_2x′)O₂ (M′=Co, Al, Ti; x=0, 0.025) cathode materials for Li-ion rechargeable batteries

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• 作者：Kang ; S.-H. ; Kim ; J. ; Stoll ; M.E. ; Abraham ; D. ; Sun ; Y.K. ; Amine ; K.
• 关键词：Lithium-ion rechargeable battery ; Cathode materials ; Lithium manganese nickel oxides ; Layered structure
• 刊名：Journal of Power Sources
• 出版年：2002
• 出版时间：October 24, 2002
• 年：2002
• 卷：112
• 期：1
• 页码：41-48
• 全文大小：261 K

文摘

Layered Li(Ni_0.5−xMn_0.5−xM_2x′)O₂ materials (M′=Co, Al, Ti; x=0, 0.025) were synthesized using a manganese-nickel hydroxide precursor, and the effect of dopants on the electrochemical properties was investigated. Li(Ni_0.5Mn_0.5)O₂ exhibited a discharge capacity of 120mAh/g in the voltage range of 2.8–4.3V with a slight capacity fade up to 40 cycles (0.09 % per cycle); by doping of 5mol % Co, Al, and Ti, the discharge capacities increased to 140, 142, and 132mAh/g, respectively, and almost no capacity fading was observed. The cathode material containing 5mol % Co had the lowest impedance, 47Ωcm², while undoped, Ti-doped, and Al-doped materials had impedance of 64, 62, and 99Ωcm², respectively. Unlike the other dopants, cobalt was found to improve the electronic conductivity of the material. Further improvement in the impedance of these materials is needed to meet the requirement for powering hybrid electric vehicle (HEV, <35Ωcm²). In all materials, structural transformation from a layered to a spinel structure was not observed during electrochemical cycling. Cyclic voltammetry and X-ray photoelectron spectroscopy (XPS) data suggested that Ni and Mn exist as Ni²⁺ and Mn⁴⁺ in the layered structure. Differential scanning calorimetry (DSC) data showed that exothermic peaks of fully charged Li_1−y(Ni_0.5−xMn_0.5−xM_2x′)O₂ appeared at higher temperature (270–290°C) than LiNiO₂-based cathode materials, which indicates that the thermal stability of Li(Ni_0.5−xMn_0.5−xM_2x′)O₂ is better than those of LiNiO₂-based cathode materials.